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Co-catalysis between DABCO and a Br?nsted acid in the catalytic [4 + 2] annulation of isatin with but-3-yn-2-one and mechanistic investigations  ( EI收录)  

文献类型:期刊文献

英文题名:Co-catalysis between DABCO and a Br?nsted acid in the catalytic [4 + 2] annulation of isatin with but-3-yn-2-one and mechanistic investigations

作者:Wang, Qiang[1]; Xu, Qin[1]; Shi, Min[1,2]

机构:[1] Key Laboratory for Advanced Materials, Institute of Fine Chemicals, East China University of Science and Technology, 130 Mei Long Road, Shanghai, 200237, China; [2] State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai, 200032, China

年份:2015

卷号:2

期号:3

起止页码:211

外文期刊名:Organic Chemistry Frontiers

收录:EI(收录号:20184806136117)

语种:英文

摘要:Catalytic amounts of the base catalyst DABCO in cooperation with a proton source (732 cation exchange resin) afford the [4 + 2] cycloadducts of isatins with but-3-yn-2-one in moderate to good yields. Moreover, related plausible mechanisms have been proposed in detail based on control and deuterium labeling experiments. ? 2015 the Partner Organisations.

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