文献类型：期刊文献

中文题名：CaO-Ca9Al6O18吸收剂的碳酸化反应动力学

英文题名：Carbonation kinetics of CO_2 with CaO-Ca_9Al_6O_(18) sorbent

作者：谢苗苗[1];周志明[1];祁阳[1];程振民[1]

机构：[1]华东理工大学,化学工程联合国家重点实验室,上海200237

年份：2013

卷号：64

期号：2

起止页码：532

中文期刊名：化工学报

外文期刊名：CIESC Journal

收录：CSTPCD;;EI(收录号：20131116114726);Scopus;北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

基金：国家自然科学基金项目(21276076);化学工程联合国家重点实验室开放课题项目(SKL-ChE-10C06);中央高校基本科研业务费项目(WA1014003)~~

语种：中文

中文关键词：CaO-Ca9Al6O18;CO2吸收剂;稳定性;碳酸化反应;动力学模型

外文关键词：CaO-Ca2Al6O18 ; CO2 sorbent ; stability; carbonation; kinetic model

摘要：以柠檬酸钙和硝酸铝为前体,采用湿法混合法制备了CaO质量分数为80%的CaO-Ca9Al6O18吸收剂,并对其CO2吸收性能进行了研究。结果表明,CaO-Ca9Al6O18具有优异的CO2吸收容量和长周期循环使用稳定性,经过50次循环使用后,其转化率仍保持在78%以上,远优于传统的CaO吸收剂。在500～700℃和CO2分压为0.005～0.015MPa条件下,研究了CaO-Ca9Al6O18吸收剂的碳酸化反应动力学,分别采用离子反应模型和表观模型描述化学反应动力学控制阶段(快反应段)和产物层扩散阶段(慢反应段)。实验测得的吸收剂转化率与模型预测值吻合较好,快慢反应段的活化能分别为25.6、57.7kJ.mol-1。该动力学模型可准确模拟CaO-Ca9Al6O18吸收剂在长周期循环使用条件下的碳酸化反应。
CaO-Ca2Al6O18 sorbent with a mass fraction of CaO of 80% was prepared by the wet mixing method. Calcium citrate and aluminum nitrate were used as calcium and aluminum precursors, respectively. The CO2 capture performance of the sorbent was investigated by using thermogravimetry. The results showed that the CaO-Ca2Al6O18sorbent exhibited excellent CO2 capture capacity and long-term cyclic stability, and its conversion remained above 770//oo after 50 consecutive cyclic operations, which was much better than that of conventional CaO sorbent. The carbonation kinetics between CO2 and the CaO-Ca2Al6O18 sorbent was then studied over a temperature range of 500--700℃and CO2 partial pressure of 0. 005--0. 015 MPa. The fast reaction regime （controlled by chemical reaction） and the slow reaction regime （controlled by diffusion） of the carbonation reaction were successfully described by an ion reaction model and an apparent model, respectively, and the corresponding activation energies were 25.6 kJ· mol^-1 and 57.7 kJ· mol^-1, respectively. The predicted conversions of the CaO-Ca2Al6O18 sorbent agreed well with the experimental data. Finally, the kinetic model established was successfully used to predict the carbonation reaction of long-term cyclic operation.