文献类型：期刊文献

英文题名：High performance carbon nanotube based composite film from layer-by-layer deposition

作者：Zhang, Liang[1];Xu, Wei[1];Luo, Xiao Gang[2];Wang, Jian Nong[1]

机构：[1]E China Univ Sci & Technol, Sch Mech & Power Engn, Nanomat Res Ctr, Shanghai 200237, Peoples R China;[2]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Shanghai 200240, Peoples R China

年份：2015

卷号：90

起止页码：215

外文期刊名：CARBON

收录：;EI(收录号：20152100869086);WOS:【SCI-EXPANDED(收录号:WOS:000356129200025)】；

基金：Financial supports from National Natural Science Foundation of China (project #: 51271077, U1362104) and Shanghai Nanoscience and Nanotechnology Promotion Center (project #: 12nm0503300) are greatly acknowledged.

语种：英文

外文关键词：Nanocomposite films - Yarn - Tensile strength - Deposition

摘要：So far, preparation of strong carbon nanotube (CNT)/polymer composites still faces big challenges mainly due to the limited controls of CNT dispersion and alignment in polymers. Here, a new "layer-by-layer deposition" method is put forward to prepare CNT/polyvinyl alcohol (PVA) composite films. This is based on intermittent deposition of aligned CNT and PVA layers on a paper tape substrate. The in situ deposition allows PVA to infiltrate into the CNT film efficiently, and, as a result, the mechanical property of CNT/PVA composite film has been improved remarkably. For example, the composite film possesses a tensile strength of 1.7 GPa, which is almost one order of magnitude and 20 times higher than those of the pure CNT and PVA films, respectively. The high performance of the composite film could be ascribed to the role of PVA infiltration, which leads to not only the formation of strong interfacial bonding between CNTs and PVA matrix but also the reduction of film thickness. The novel process offers a new research direction for preparing CNT-based composites and future performance maximization. (C) 2015 Elsevier Ltd. All rights reserved.