文献类型：期刊文献

英文题名：Carbon as a hard template for nano material catalysts

作者：Zhu, Kake[2];Sun, Junming[1,3];Zhang, He[1];Liu, Jun[3];Wang, Yong[1,3]

机构：[1]Washington State Univ, Gene & Linda Voiland Sch Chem Engn & Bioengn, Pullman, WA 99164 USA;[2]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[3]Pacific NW Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA

年份：2012

卷号：21

期号：3

起止页码：215

外文期刊名：JOURNAL OF NATURAL GAS CHEMISTRY

收录：;EI(收录号：20122415105983);WOS:【SCI-EXPANDED(收录号:WOS:000305776100002)】；

基金：We gratefully acknowledge the US Department of Energy (DOE), Basic Energy Sciences, Division of Chemical Sciences, Bio-sciences and Geosciences for the support of this work. KZ is grateful for the financial support from the National Natural Science Foundation of China (21006024), Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry, Fudan University (No. 2010MCIMKF), Fundamental Research Funds for the Central Universities (WA0914023), and CPNP Foundation (2011D-5006-0507), and is also sponsored by the Shanghai Pujiang Program (11PJ1402600) for talented returnees.

语种：英文

外文关键词：carbon; template; catalysis; nanomaterial; hierarchy

摘要：As one of the naturally abundant elements, carbon can present in different molecular structures (allotropes) and thus lead to various physical/chemical properties of carbon-based materials which have found wide applications in a variety of fields including electrochemistry, optical, adsorption and catalysis, etc. On the other hand, its different allotropes also endow carbon-based materials with various morphostructures, which have been recently explored to prepare oxides and zeolites/zeotypes with tailored structures. In this review, we mainly summarize the recent advances in using carbon materials as hard templates to synthesize structural materials. Specifically, we focus on the development in the synthetic strategies, such as endotemplating, exotemplating approaches and using carbon materials as chemical reagents for the synthesis of metal carbides or nitrides, with an emphasis laid on the control of morphostructure. Meanwhile, the applications of the obtained materials will be highlighted, especially, in the field of heterogeneous catalysis where enhanced performances have been achieved with the materials derived from carbon-templated methods.