文献类型：期刊文献

英文题名：A highly efficient kinetic resolution of Morita-Baylis-Hillman adducts achieved by N-Ar axially chiral Pd-complexes catalyzed asymmetric allylation

作者：Wang, Feijun[1,2];Li, Shengke[1,2];Qu, Mingliang[1,2];Zhao, Mei-Xin[1,2];Liu, Lian-Jun[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2011

卷号：47

期号：48

起止页码：12813

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000297364100021)，CCR-EXPANDED(收录号:WOS:000297364100021)】；

基金：Financial support from the National Natural Science Foundation of China (21072206, 20902019, 20472096, 20872162, 20672127, 20821002 and 20732008), the National Basic Research Program of China (973)-2010CB833302, and the Fundamental Research Funds for the Central Universities (WJ1014034 and WK1013004) is gratefully acknowledged.

语种：英文

摘要：Palladium complexes with an axially chiral N-Ar framework have been developed. These complexes showed high stereoselectivities in asymmetric allylic arylation to achieve the kinetic resolution of Morita-Baylis-Hillman adducts, affording up to 99% ee of (E)-allylation products and 92% ee of recovered Morita-Baylis-Hillman adducts.