文献类型：期刊文献

英文题名：Preparation of high oxygen storage capacity and thermally stable ceria-zirconia solid solution

作者：Li, Jie;Liu, Xiaofei;Zhan, Wangcheng;Guo, Yun;Guo, Yanglong;Lu, Guanzhong[1,2]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China

年份：2016

卷号：6

期号：3

起止页码：897

外文期刊名：CATALYSIS SCIENCE & TECHNOLOGY

收录：;EI(收录号：20160701920382);WOS:【SCI-EXPANDED(收录号:WOS:000369533400035)】；

基金：This project was financially supported by the National Natural Science Foundation of China (21273150, 21171055), the National Basic Research Program of China (2013CB933201), the National High Technology Research and Development Program of China (2011AA03A406, 2012AA111717), and Fundamental Research Funds for the Central Universities (WK1214007).

语种：英文

外文关键词：Catalyst activity - Solid solutions - Calcination - Coprecipitation - Emission control - Storage (materials) - Oxygen - Thermodynamic stability - Zirconia - Cerium oxide - Catalytic oxidation

摘要：Ceria-zirconia solid solution is a very important material in three-way catalysts for automotive emission control. High oxygen storage capacity (OSC) and thermally stable Ce0.5Zr0.5O2 was prepared by a modified complexing-coprecipitation (CC) method, and its surface area reached 44 m(2) g(-1) after calcination at 1100 degrees C for 6 h. Based on the characterizations of its structural and physicochemical properties, it was found that Ce0.5Zr0.5O2 prepared by the CC method existed as the t ''-phase with rich oxygen defects and surface Ce3+ and has a larger BET surface area, uniform particle and pore sizes, and excellent bulk oxygen migration and redox abilities than samples prepared by other methods. After being calcined at 1100 degrees C for 6 h, its surface area, OSC (and OSCC, oxygen storage capacity complete) and catalytic activity for the oxidation of CO were still the best among three Ce0.5Zr0.5O2 solid solutions prepared by three methods whether it was used as the catalyst or as a support for a Pd catalyst, reflecting its good thermostability, although its particle and pore sizes were somewhat increased. This complexing-coprecipitation method can be used to prepare other high surface area and thermally stable inorganic materials.