文献类型：期刊文献

英文题名：Recent Advances in RAFT Polymerization: Novel Initiation Mechanisms and Optoelectronic Applications

作者：Tian, Xiangyu[1,2];Ding, Junjie[1,2];Zhang, Bin[1,2];Qiu, Feng[3,4];Zhuang, Xiaodong[3,4,5,6];Chen, Yu[1,2]

机构：[1]East China Univ Sci & Technol, Inst Appl Chem, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Inst Appl Chem, Shanghai Key Lab Funct Mat Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, State Key Lab Met Matrix Composites, Dongchuan Rd 800, Shanghai 200240, Peoples R China;[4]Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai Key Lab Elect Insulat & Thermal Ageing, Dongchuan Rd 800, Shanghai 200240, Peoples R China;[5]Tech Univ Dresden, Ctr Adv Elect Dresden CFAED, D-01062 Dresden, Germany;[6]Tech Univ Dresden, Dept Chem & Food Chem, D-01062 Dresden, Germany

年份：2018

卷号：10

期号：3

外文期刊名：POLYMERS

收录：;EI(收录号：20181204925607);WOS:【SCI-EXPANDED(收录号:WOS:000428388200092)】；

基金：The authors are grateful for the financial support of the National Natural Science Foundation of China (51333002, 21404037, 61378072), Research Fund for the Doctoral Program of Higher Education of China (20120074110004), the Fundamental Research Funds for the Central Universities (WJ1514311), the Chenguang Program (15CG28), and the Pujiang Program (16PJ1402400). Xiaodong Zhuang acknowledge the financial support from NSFC for Excellent Young Scholars (51722304), NSFC (5171101862, 21720102002), Shanghai Committee of Science and Technology (15JC1490500, 16JC1400703), and Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment (SKLPEE-KF201702, Fuzhou University).

语种：英文

外文关键词：RAFT polymerization; chain transfer agent; initiation method; optoelectronic applications

摘要：Reversible addition-fragmentation chain transfer (RAFT) is considered to be one of most famous reversible deactivation radical polymerization protocols. Benefiting from its living or controlled polymerization process, complex polymeric architectures with controlled molecular weight, low dispersity, as well as various functionality have been constructed, which could be applied in wide fields, including materials, biology, and electrology. Under the continuous research improvement, main achievements have focused on the development of new RAFT techniques, containing fancy initiation methods (e.g., photo, metal, enzyme, redox and acid), sulfur-free RAFT system and their applications in many fields. This review summarizes the current advances in major bright spot of novel RAFT techniques as well as their potential applications in the optoelectronic field, especially in the past a few years.