文献类型：期刊文献

英文题名：Synthesis of Z-alkenes via visible light promoted photocatalytic E → Z isomerization under metal-free conditions

作者：Cai, Wenbin[1];Fan, Huaqiang[1];Ding, Dazhong[2];Zhang, Yongqiang[1];Wang, Wei[1,3]

机构：[1]East China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China;[2]Qingdao Inst Food & Drug Control, Qingdao 266000, Peoples R China;[3]Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA

年份：2017

卷号：53

期号：96

起止页码：12918

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000416804400012)，CCR-EXPANDED(收录号:WOS:000416804400012)】；

语种：英文

摘要：A green approach for the synthesis of thermodynamically less stable Z-alkenes has been presented through the exploration of visible light promoted photocatalytic E-to-Z isomerization. This protocol features metal-free conditions, which is operationally simple, remarkably clean, and allows the synthesis of both electron-rich and electron-deficient Z-alkenes with diverse functional groups.