文献类型：期刊文献

英文题名：An efficient route to highly enantioenriched tetrahydroazulenes and β-tetralones by desymmetrization reactions of δ,δ-diaryldiazoaceto-acetates

作者：Liu, Yuxiao[1,2];Deng, Yongming[1];Zavalij, Peter Y.[1];Liu, Renhua[2];Doyle, Michael P.[1]

机构：[1]Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA;[2]E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

年份：2015

卷号：51

期号：3

起止页码：565

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000346068200028)，CCR-EXPANDED(收录号:WOS:000346068200028)】；

基金：Support for this research from the National Science Foundation (CHE-1212446) is gratefully acknowledged. Yuxiao Liu received financial support from the China Scholarship Council (CSC).

语种：英文

摘要：A highly stereoselective desymmetrization reaction of delta,delta-diaryl-alpha-diazo-beta-ketoesters catalyzed by chiral dirhodium carboxylates forms aromatic cycloaddition products in up to 97% ee.