文献类型：期刊文献

英文题名：An efficient multi-path to active peroxymonosulfate by carbon and sulfur co-doped boron nitride for antibiotics degradation: An emerging electron-transfer pathway at activated-S sites

作者：Zhao, Qingzi[1,2];Liu, Da[1,2];Wu, Yizhou[1,2];Zhou, Liang[1,2,3,4];Lu, Sitong[5];Lei, Juying[1,2,3,4];Zhang, Jinlong[4,6,7];Liu, Yongdi[1,2,4]

机构：[1]East China Univ Sci & Technol, Natl Engn Res Ctr Ind Wastewater Detoxicat & Resou, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, State Environm Protect Key Lab Environm Risk Asses, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China;[4]East China Univ Sci & Technol, Shanghai Engn Res Ctr Multimedia Environm Catalysi, 130 Meilong Rd, Shanghai 200237, Peoples R China;[5]Shanghai Geol Engn Explorat Grp Co Ltd, Shanghai 200072, Peoples R China;[6]East China Univ Sci & Technol, Feringa Nobel Prize Scientist Joint Res Ctr, Sch Chem & Mol Engn, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[7]East China Univ Sci & Technol, Joint Int Res Lab Precis Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2025

卷号：352

外文期刊名：SEPARATION AND PURIFICATION TECHNOLOGY

收录：;EI(收录号：20242416227680);WOS:【SCI-EXPANDED(收录号:WOS:001252287200001)】；

基金：This work was financially supported by the National Natural Science Foundation of China (22176061, 22076046) , the Science and Technology Commission of Shanghai Municipality (21230712000) , and the Shanghai Pujiang Program (21PJD016) .

语种：英文

外文关键词：Editor: Shujuan Zhang; Peroxymonosulfate activation; Boron nitride; Co -doping; Multi-pathways; Electron transfer

摘要：Metal-free catalysis is considered promising for the green degradation of aqueous organic pollutants. Herein, a novel non-metallic heteroatom-doped boron nitride (h-BN) catalyst with carbon and sulfur doping, named SC-BN, was successfully prepared. Under optimal conditions, the SC-BN/peroxymonosulfate (PMS) system can achieve an impressive 99.4 % levofloxacin removal within 90 min (k(obs) = 0.0531 min(-1)). In-depth physicochemical characterizations have identified B-N-C and C-S-C as co-active functional groups. The electrochemical characterization and density functional theory (DFT) calculations further verified the enhanced electron transfer pathway (ETP) at S sites, which was activated by an emerging electric field. h-BN as a highly electroactive material also plays a positive role in regulation. Besides, the electrical energy per order (EE/O = 6.65 kWh/m(3)) and toxicity evaluation results exhibited the practical potential for eco-friendly detoxification and degradation of various refractory contaminants. In summary, this study puts forth a novel metal-free PMS activation process with an efficient multi-path mechanism and provides a theoretical foundation for future research.