文献类型：期刊文献

英文题名：Regulating a two-dimensional metallo-supramolecular self-assembly of multiple outputs

作者：Shi, Ziliang[1];Lin, Tao[1];Liu, Jun[2,3];Liu, Pei Nian[2,3];Lin, Nian[1]

机构：[1]Hong Kong Univ Sci & Technol, Dept Phys, Hong Kong, Hong Kong, Peoples R China;[2]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2011

卷号：13

期号：18

起止页码：5532

外文期刊名：CRYSTENGCOMM

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000294178100002)】；

基金：This work is financially supported by Hong Kong RGC under Grant No. 602409, the National Natural Science Foundation of China (Project No. 20902020) and Shanghai Pujiang Talent Program (Project No. 09PJ1403500).

语种：英文

摘要：On a Au(111) surface, a mixture of two types of molecular ligands assembles with Cu generating two homogeneous and one heterogeneous metallo-supramolecular structures owing to same pyridyl-Cu-pyridyl coordination. The proportion of the three phases in the output structures is regulated by adjusting the ratio of the two components in the input molecular mixture. As the ratio approaches the stoichiometric value of the heterogeneous structure, one of the ligands is 100% incorporated in the heterogeneous phase, manifesting a unique amplification behaviour in this multiple output self-assembly.