文献类型：期刊文献

英文题名：Catalytic Mechanisms and Active Species of Benzene Hydroxylation Reaction System Based on Fe-Based Enzyme-Mimetic Structure

作者：Wang, Yongjie[1];Wang, Jinling[1,2];Wei, Jie[1];Wang, Chenglong[1];Wang, Hualin[1];Yang, Xuejing[1,2]

机构：[1]East China Univ Sci & Technol, Natl Engn Res Ctr lndustrial Wastewater Detoxicat, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2023

卷号：153

期号：11

起止页码：3311

外文期刊名：CATALYSIS LETTERS

收录：;EI(收录号：20225113278323);WOS:【SCI-EXPANDED(收录号:WOS:000899121900002)】；

基金：AcknowledgementsThis work was partially supported by the authors are grateful for the support from the National Key Projects for Fundamental Research and Development of China (2019YFC1906700) and the National Natural Science Foundation of China (21876049, 22222602).

语种：英文

外文关键词：Benzene hydroxylation; Fe-based catalyst; Enzyme-mimetic materials; Heterogeneous catalysis

摘要：Subject to the shortcomings of traditional heterogeneous materials (such as the limited controllability of the preparation process, the complex surface structures and the dynamic evolution of surface structures), many scholars have been inspired by natural enzyme systems (e.g. monooxygenases and peroxidases) to innovate the catalytic system for C-H bond activation. The structure and catalytic performance of the high-valent Fe-O intermediates in metalloenzymes have been well studied for this purpose. This review will firstly introduce the natural Fe-based metalloenzymes and synthetic Fe complexes, and briefly summarize their structures and catalytic mechanisms, especially for C-H bond activation. Then, the structural characteristics and research progress of four representative Fe-based enzyme-mimetic materials were reviewed. These Fe-based metalloenzymes with unique coordination environment active sites and their powerful catalytic ability will provide a good reference for the field of heterogeneous catalysis. [GRAPHICS]