文献类型：期刊文献

英文题名：Studies on synthesis of graft copolymers with p-chloromethylstyrene copolymers as macroinitiators

作者：Zhang, YM; Luo, N; Ying, SK

机构：[1]E China Univ Sci & Technol, Lab Living Polymerizat, Shanghai 200237, Peoples R China

年份：1999

卷号：20

期号：3

起止页码：492

外文期刊名：CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE

收录：;EI(收录号：1999084764381);WOS:【SCI-EXPANDED(收录号:WOS:000081285900041)】；

语种：英文

外文关键词：p-chloromethylstyrene; macroinitiator; ATRP; graft-copolymer

摘要：A series of graft copolymers were synthesized by ATRP initiated with macroinitiators which had been made from copolymerization of p-chloromethylstyrene and other monomers, such as methyl methacrylate, butyl methacrylate, acrylonitrile, styrene, vinyl acetate, isobutene-maleic anhydride, styrene-maleic anhydride etc.. The graft copolymers were characterized by IR and H-1 NMR spectra. The numbers of graft points or the branches on the graft copolymers were determined by Ion Chromatography. The design for the various structures and architectures of the graft copolymers was made by changing the compositions of the backbones and the branches. The results indicated that it is a versatile route to synthesize a lot of graft copolymers and will be commercially important in the future.