文献类型：期刊文献

中文题名：拉曼光谱在玉石无损鉴别中的应用

英文题名：Application of Raman Spectroscopy to the Noninvasive Identification of Jade

作者：薛蕾[1];王以群[1];范建良[1]

机构：[1]华东理工大学材料科学与工程学院,上海200237

年份：2009

卷号：35

期号：6

起止页码：857

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心2008】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：拉曼光谱;软玉;蛇纹石玉;石英岩玉;大理岩玉

外文关键词：Raman spectroscopy nephrite serpentine quartzite marble

摘要：通过对软玉及相似玉石蛇纹石玉、石英岩玉、大理岩玉、白色玻璃的拉曼光谱进行测试与研究,得到软玉具有由Si—O振动引起的特征拉曼位移672,930,1 057 cm-1;蛇纹石玉具有由Si—O振动引起的特征拉曼位移678 cm-1和1 041 cm-1,由Mg—O引起的特征拉曼位移369 cm-1;石英岩玉具有由Si—O振动引起的特征拉曼位移460 cm-1;大理岩玉具有由CO32-引起的特征拉曼位移1 080 cm-1;白色玻璃具有特征拉曼位移1 353 cm-1。根据拉曼位移的位置和强度,可无损、快速、有效地区分软玉、蛇纹石玉、石英岩玉、大理岩玉、白色玻璃。
Raman spectroscopy was used to characterize nephrite,serpentine,quartzite,marble and white glass,it is found that the characteristic Raman shifts of nephrite which are caused by Si—O vibration are 672,930,（1 057 cm-（-1））;the characteristic Raman shifts of serpentine which are caused by Si—O vibration are 678 cm-（-1） and（1 041 cm-（-1））,which are caused by Mg—O vibration is 369 cm-（-1）;the characteristic Raman shift of quartzite which are caused by Si—O vibration is 460 cm-（-1）;the characteristic Raman shift of marble which are caused by CO--（2-）__3 vibration is （1 080 cm-（-1））;the characteristic Raman shift of white glass is （1 353cm-（-1））.According to the position and intensity of each characteristic Raman shift,nephrite,serpentine,quartzite,marble and white glass can be quickly and effectively set apart without any damage to these gemstones.