文献类型：期刊文献

中文题名：新型2－硫代苯并咪唑磺酰亚胺盐类在卤化银乳剂中的超增感

英文题名：Supersensitization of New 2-Thiobenzimidazolylsulfonylimidate Compounds in Silver Halide Emulsion

作者：胡倩琪[1];段彩明[1];焦锐[1];陈涛[1]

机构：[1]华东理工大学精细化工系,华东理工大学化学系

年份：1994

卷号：20

期号：1

起止页码：26

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;EI(收录号：1994111415290);Scopus;CSCD:【CSCD2011_2012】；

基金：上海自然科学基金

语种：中文

中文关键词：磺酰亚胺盐;卤化银乳剂;超增感

外文关键词：sensitization;electron spin resonance; emulsion;supersensitizei;supersensiti-zing;sodium-N,N’- di(arylsulfonyl )-s-(2-thiobenzimidazolyl)sulfonylimidate;polarographic half- wave potential

摘要：通过电子自旋共振（ＥＳＲ）技术、染料的极谱分析以及在乳剂中的应用试验，对文题化合物与中位乙基取代的噻碳菁染料进行超增感组合研究。结果表明：超增感作用与ＥＳＲ信号、极谱半波电位之间有一定关系，当超增感剂的氧化电位值低于增感染料，且小于＋０．８８Ｖ时，光谱增感效果提高，ＥＳＲ信号强度亦增强。其超增感作用的产生可用正穴捕获超增感机理加以阐明。
The optical sensitization of 2- thiobenzimidazolylsulfonylimidate and meso-posi-tion ethyl substituted thiocarbocyanine dyes was studied. Electron Spin Resenance(ESR)and polarographic measurement of dyes and photographic emulsion tests show that efficiency of the supersensitizing combination is connected with ESR signal and polalographic half- wave poten-tial.When the oxidation potential of supersensitizer is below 0.88V,and lower than the oxidation potential of the sensitizer,the photographic sensitivity of this system is raised and so does the intensity of ESR signals. The function of supersensitization can be explained by the hole trapping mechanism.