文献类型：期刊文献

英文题名：MOFs materials as photocatalysts for CO2 reduction: Progress, challenges and perspectives

作者：Khan, Mazhar[1];Akmal, Zeeshan[1];Tayyab, Muhammad[2];Mansoor, Seemal[1];Zeb, Adnan[1];Ye, Ziwei[1];Zhang, Jinlong[1];Wu, Shiqun[1];Wang, Lingzhi[1]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat, Feringa Nobel Prize Scientist Joint Res Ctr, Sch Chem & Mol Engn,Joint Int Res Lab Precis Chem, Shanghai 200237, Peoples R China;[2]Tsinghua Univ, Inst Mat Res, Tsinghua Shenzhen Int Grad Sch, Shenzhen 518055, Guangdong, Peoples R China

年份：2024

卷号：11

外文期刊名：CARBON CAPTURE SCIENCE & TECHNOLOGY

收录：WOS:【ESCI(收录号:WOS:001170944600001)】；

基金：This study was supported by National Key R&D Program of China (2021YFC2103500) , National Natural Science Foundation of China (21972040 and 22202070) , the Science and Technology Commission of Shanghai Municipality (21ZR1417900) , the Innovation Program of Shanghai Municipal Education Commission (2021-01-07-00-02-E00106) , the Fundamental Research Funds for the Central Universities , the Postdoctoral Innovative Talent Support Program (BX20220107) , the Shanghai Rising-Star Program (22YF1410200) , and the Shanghai Super Postdoctoral Fellow.

语种：英文

外文关键词：MOFs; Photocatalysis; CO2 reduction; Porosity

摘要：Photocatalytic reduction of carbon dioxide (CO2) presents a pivotal solution to address meteorological and ecological challenges. Currently, metal -organic frameworks (MOFs) with their crystalline porosity, adjustable structures, and diverse chemical functionalities have garnered significant attention in the realm of photocatalytic CO2 reduction. This review provides a brief introduction to CO2 reduction and MOF material and their applications in CO2 reduction. Then, it undertakes a comprehensive examination of MOFs, summarizing their key attributes, including porosity, large surface area, structural multifunctionalities, and responsiveness to visible light, along with an analysis of heterojunctions and their methods of preparation. Additionally, it elucidates the fundamental principle of photocatalysis and CO2 reduction, encompassing both half and overall reactions. Furthermore, the classification of MOF-based materials is explored, along with the proposed mechanism for CO2 reduction and an update on recent developments in this field. Finally, this review outlines the challenges and potential opportunities for utilizing MOFs in CO2 reduction, offering valuable insights to scholars seeking innovative approaches not only to enhance CO2 reduction but also to advance other photocatalytic processes.