详细信息
文献类型:期刊文献
中文题名:含钛沸石催化氧化性能研究的新进展
英文题名:Recent Progress of Study on the Catalytic Oxidative Properties of Ti-zeolites
作者:万颖[1];卢冠忠[1];王幸宜[1]
机构:[1]华东理工大学工业催化研究所,上海200237
年份:1999
卷号:18
期号:1
起止页码:29
中文期刊名:化工进展
外文期刊名:Chemical Industry and Engineering Progress
收录:CSTPCD;;Scopus;CSCD:【CSCD2011_2012】;
基金:上海市优秀学科带头人计划;上海市曙光计划资助项目
语种:中文
中文关键词:含钛沸石;催化氧化;过氧化氢;有机化合物;作用机理;催化活性;杂原子沸石
外文关键词:Ti-zeolites, catalytic oxidation, hydrogen peroxide, organic compound
摘要:评述了含钛沸石催化低浓度H_2O_2氧化有机化合物最新的研究进展,重点叙述了含钛沸石在酚的氧化、烯烃的环氧化、胺的氧化、饱和烃的氧化等反应中的应用及催化作用机理,并对不同种类含钛沸石间催化活性的差异进行了比较.
In this paper the recent progress of study on the catalytic behaviors of zeolites containing Ti for the oxidation of the organic compounds by a low concentration H202 is reviewed. These selective oxidative reactions involve the hy-droxylation of phenol, epoxidation of alkenes, oxidation of amines, alkanes and etc. For the reaction mentioned above, the catalytic mechanism and difference between Ti-zeolites have also been discussed.
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