文献类型：期刊文献

英文题名：Macroporous Cross linked Polymers with Controlled Structure Fabricated via Low Temperature Phase-Separation Photopolymerization

作者：Yin, Ruixue[1];Wang, Kemin[2];Lu, Yuhui[2];Nie, Jun[3]

机构：[1]E China Univ Sci & Technol, Sch Mech & Power Engn, Complex & Intelligent Res Ctr, Shanghai, Peoples R China;[2]Changzhou Univ, Sch Mat Sci & Engn, Changzhou 213164, Peoples R China;[3]Beingjing Univ Chem Technol, Sch Mat Sci & Engn, Beijing Key Lab Biomed Mat, Beijing, Peoples R China

年份：2015

卷号：300

期号：3

起止页码：291

外文期刊名：MACROMOLECULAR MATERIALS AND ENGINEERING

收录：;EI(收录号：20150500477137);WOS:【SCI-EXPANDED(收录号:WOS:000351654000004)】；

基金：The authors would like to thank the National Natural Science Foundation of China (21304011) and the Postdoctoral Science Foundation of China (J200-2R-14036).

语种：英文

外文关键词：crosslinked; low temperature phase-separation; macroporous polymers; photopolymerization

摘要：Macroporous polymers are of great interest and are used in diverse fields including filtration, catalysts, tissue engineering, and bioseparation. Great efforts have been invested in the manipulation of macroporous polymers. However, the straightforward fabrication of porous polymers with controlled structures from the corresponding monomers remains challenging. This study proposes a general, simple route for the synthesis of macroporous crosslinked polymers with 2D or 3D shape from the corresponding monomers by low temperature phase-separation photopolymerization with no template and no surfactant or other additives. The generality of this approach makes synthesis possible from any type of monomer that can be photopolymerized, thus offering wide tunability of polymer properties for various applications. We believe that this strategy has great potential to be used widely for the fabrication of macroporous polymer membranes or monoliths in the future.