文献类型：期刊文献

英文题名：Cobalt-Catalyzed Borylation of Aryl Halides and Pseudohalides

作者：Yao, Wubing[1,2];Fang, Huaquan[2];Peng, Sihan[2];Wen, Huanan[2];Zheng, Lei[2];Hu, Aiguo[1];Huang, Zheng[2]

机构：[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai Key Lab Adv Polymer Mat, Shanghai 200237, Peoples R China;[2]Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

年份：2016

卷号：35

期号：10

起止页码：1559

外文期刊名：ORGANOMETALLICS

收录：;EI(收录号：20162302460028);WOS:【SCI-EXPANDED(收录号:WOS:000376548400032)，CCR-EXPANDED(收录号:WOS:000376548400032)】；

基金：We acknowledge financial support from the National Basic Research Program of China (2015CB856600), the National Natural Science Foundation of China (No. 21422209, 21432011, 21272255, and 21421091), and the CAS/SAFEA International Partnership Program for Creative Research Teams.

语种：英文

外文关键词：Synthesis (chemical) - Cobalt compounds - Chelation - Metal halides - Catalysis - Chlorine compounds

摘要：We report the first Co-catalyzed borylation of aryl halides and pseudohalides with bis(pinacolato)diboron (B(2)pin(2)). The synthesis of two new Co(II) complexes of oxazolinylferrocenylphosphine ligands is described. Upon activation with LiMe, the Co complex catalyzes the borylation reactions of aryl bromides, iodides, sulfonates, 0arenediazonium salts, and even aryl chlorides under mild conditions, providing the borylated products in excellent to moderate yields and with high functional group tolerance.