文献类型：专利

英文题名：Selective oxidation of cyclohexane involves oxidizing cyclohexane in presence of cerium-supported mesoporous molecular sieve catalyst, t-butyl hydroperoxide and oxygen and obtaining cyclohexanol/cyclohexanone reaction product

作者：LU G;WANG J;ZHANG Z;ZHAN W;FU Y;GUO Y;LIU S;WANG Y;CHAI G;SUI Y

机构：[1]UNIV EAST CHINA SCI & TECHNOLOGY

申请号：CN103965014-A

申请日：2014-05-15

公开日：2014-08-06

语种：英文

收录：DERWENT

摘要：NOVELTY - Selective oxidation of cyclohexane involves adding cyclohexane as reactant into a reactor, adding cerium-supported surface functionalized MCM-48 mesoporous molecular sieve catalyst, adding 10 mu l t-butyl hydroperoxide, introducing oxygen as oxidant under pressure of 1 MPa, reacting at 120-160 degrees C for 4 hours, and obtaining reaction product of cyclohexanol and cyclohexanone. The selective oxidation of cyclohexane is carried out without using a solvent. USE - Selective oxidation of cyclohexane (claimed). ADVANTAGE - The method efficiently oxidizes cyclohexane and provides cyclohexanol/cyclohexanone reaction product having selectivity of 85.7%, with high catalytic activity and cyclohexane conversion rate of 9.2%.