文献类型：期刊文献

中文题名：氟氮掺杂的有序介孔碳材料合成实验研究

英文题名：Study on experiment of synthesis of ordered mesoporous carbon materials doped with fluorine and nitrogen

作者：殷馨[1];刘嘉威[1];赵丹[1];周志明[1];杨泽仁[1];王海文[1]

机构：[1]华东理工大学化学与分子工程学院,上海200237

年份：2017

卷号：34

期号：7

起止页码：49

中文期刊名：实验技术与管理

外文期刊名：Experimental Technology and Management

收录：北大核心:【北大核心2014】；

基金：上海高校实验技术队伍建设计划资助项目(YJ0114204;YJ0114208)

语种：中文

中文关键词：介孔碳;氟氮掺杂;非金属

外文关键词：mesoporous carbon; fluorine doped nitrogen; non-metals

摘要：采用硬模板法,使用价格低廉的间苯二酚作为炭前驱体,采用氟化铵作为氟氮来源,合成氟氮掺杂的有序介孔碳(F-N-OMC)。在1 000℃时制备的氟氮掺杂的有序介孔碳材料中,大量的氟氮原子(F原子数分数为0.35%,N为2.25%)均匀注入到高表面积的石墨化碳基体(671.3cm^2/g)和有序介孔通道内(6.2nm)。碳骨架内的氟氮原子的合成效果可以显著地极化相邻碳原子,并推动由缺陷引发的氧还原反应活性部位的形成。这将有助于氧还原反应性能的提高,因此氟氮掺杂的介孔碳材料有望成为高效的氧还原反应催化剂。
By adopting a hard template method,the ordered mesoporous Kong Tan（F-N-OMC）doped with fluorine nitrogen is synthesized by using inexpensive resorcinol as carbon precursor and ammonium fluoride as a fluorine and nitrogen source.Considerable fluorine and nitrogen atoms（F：0.35at%,N：2.25at%）are homogeneously implanted in the graphitic carbon matrix with high surface area（671.3cm^2/g）and ordered mesoporous channels（6.2nm）of FN-OMC prepared at the optimized heat-treatment temperature of 1 000℃.The synergistic effect of fluorine and nitrogen atoms in carbon frameworks is demonstrated to sharply polarize adjacent carbon atoms and promote the formation of the active sites of oxygen reduction reactions induced by defects.This will help to improve the performance of oxygen reduction reaction.Therefore,the FN-OMC is expected to become an efficient catalyst for oxygen reduction reaction.