文献类型：期刊文献

英文题名：Supramolecular polymer assembly in aqueous solution arising from cyclodextrin host-guest complexation

作者：Wang, Jie[1];Qiu, Zhiqiang[1];Wang, Yiming[1];Li, Li[1];Guo, Xuhong[1];Duc-Truc Pham[2];Lincoln, Stephen F.[2];Prud'homme, Robert K.[3]

机构：[1]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia;[3]Princeton Univ, Dept Chem Engn, Princeton, NJ 08544 USA

年份：2016

卷号：12

起止页码：50

外文期刊名：BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000368063300001)】；

基金：This work was supported by the NSFC Grants 51403062, 51273063 and 20774030, the Fundamental Research Funds for the Central Universities, China Postdoctoral Science Foundation (2013M541485), 111 Project Grant (B08021) and the Australian Research Council Grant DP110103177.

语种：英文

外文关键词：cyclodextrin; host-guest; polymer; smart-material; supramolecular

摘要：The employment of cyclodextrin host-guest complexation to construct supramolecular assemblies with an emphasis on polymer networks is reviewed. The main driving force for this supramolecular assembly is host-guest complexation between cyclodextrin hosts and guest groups either of which may be discrete molecular species or substituents on a polymer backbone. The effects of such complexation on properties at the molecular and macroscopic levels are discussed. It is shown that cyclodextrin complexation may be used to design functional polymer materials with tailorable properties, especially for photo-, pH-, thermo- and redox-responsiveness and self-healing.