文献类型：期刊文献

中文题名：神府烟煤和黄天棉褐煤的快速热解

英文题名：Rapid Pyrolysis of Shenfu Bituminous Coal and Huantianmian Lignite

作者：王杰[1];颜涌捷[1];薛为岚[1];陈林[1];王劲[1]

机构：[1]华东化工学院能源化工系

年份：1993

卷号：19

期号：4

起止页码：432

中文期刊名：华东化工学院学报

收录：国家哲学社会科学学术期刊数据库;Scopus;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：烟煤;褐煤;热解;动力学

外文关键词：coal; iapid pyrolysis; gaseous products; kinetics

摘要：用电加热金属丝网技术研究了文题。用冷阱(-196℃)捕集CO_2、CO、CH_4、C_2H_4和C-2H_6等气相组成,由气相色谱测定各气相组分析出率。考察了保温加热和脉冲加热时,挥发分析出率和各气相组成析出率随温度变化的规律。根据总包单反应模型,计算了升温过程中总挥发分析出和各气相组成析出的动力学参数。
Yields of total volatile and gaseous products from rapid pyrolysis have been determined for two kinds of chinese coal (shenfu bituminous coal and Huantianmian lignite) in an electrically heated grid reactor with lipophilic traps which were used to collect gaseous products. Heating rate, peak temperature and residence time at peak temperature were varied in the ranges of 500～1000℃/s, 400～950℃ and 1 or 12 s. The variation of yields of total volatile and all gaseous products with peak temperature was examined. Secondary reactions of tar escaping immediately from heated region could account for to a little greater extent the increasing yield of carbon dioxide at higher temperatures. It is shown that yields of total volatile and all gaseous products during pulse heating were lower than those at holding temperature, but approached the latter at higher temperatures. The kinetic parameters for production of total volatile, carbon dioxide, carbon monoxide and methane were calculated with single reaction model.