文献类型：期刊文献

英文题名：Conversion from ?-spodumene to intermediate product Li2SiO3 by hydrothermal alkaline treatment in the lithium extraction process

作者：Qiu, Shengbo[1];Liu, Chenglin[1,2];Yu, Jianguo[1,2]

机构：[1]East China Univ Sci & Technol, Natl Engn Res Ctr Integrated Utilizat Salt Lake Re, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Joint Int Lab Potassium & Lithium Strateg Resource, Shanghai 200237, Peoples R China

年份：2022

卷号：183

外文期刊名：MINERALS ENGINEERING

收录：;EI(收录号：20221912087701);WOS:【SCI-EXPANDED(收录号:WOS:000810452700003)】；

基金：Acknowledgements This work was supported by National Key R&D Program of China (2021YFC2902603) and Shanghai Pujiang Program (2019PJD011) .

语种：英文

外文关键词：alpha-spodumene; Hydrothermal alkaline treatment; Li2SiO3; Acid leaching; Lithium extraction

摘要：The key to the lithium extraction from alpha-spodumene is destroying the crystal structure. The conventional commercial process requires high-temperature calcination to transform alpha-spodumene into beta-spodumene. This study aimed at finding an alternative treatment for destroying the structure of alpha-spodumene and extracting the lithium. The results indicated that alpha-spodumene could be directly decomposed by NaOH solution and the Li element in alpha-spodumene was converted into intermediate product Li(2)SiO(3)in the form of solid phase under certain conditions. According to the experiments, the possible reactions during the hydrothermal alkaline treatment were predicted, which were thermodynamically possible by the calculation of Gibbs free energy using HSC Chemistry 10. The total extraction efficiency of Li2O was 87.3%, including the extraction efficiency of Li2O leached into liquid phase, 7.6%, and converted into Li2SiO3, 79.7%, obtained under optimal conditions: stirring speed of 500 rpm, leaching temperature of 250 C, mass ratio of NaOH/ore of 1.5, initial NaOH concentration of 25 wt%, and leaching time of 24 h. Then the Li element in the Li(2)SiO(3 )could be extracted by acid leaching and precipitated using Na2CO3. The mother liquor obtained after hydrothermal alkaline treatment was reused for the subsequent hydrothermal alkaline cyclic leaching under the above conditions. During three cycles of alkaline treatment, the alpha-spodumene decomposition was stable, and the total Li2O extraction efficiency was around 86% (~84% was converted into Li2SiO3). This process avoids high-temperature calcination and concentrated acid roasting, where the acid leaching process is carried out at room temperature.