文献类型：期刊文献

英文题名：Improvement of the Interfacial Shear Strength of Poly(p-phenylene benzobisoxazole) Fiber/Epoxy Resin Composite via a Novel Surface Coating Agent

作者：Liu, Rongbiao[1];Han, Zhewen[1];Li, Weifeng[1];Li, Xinxin[1];Zhuang, Qixin[1]

机构：[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Dept Polymer Sci, Key Lab Ultrafine Mat,Minist Educ, Shanghai 200237, Peoples R China

年份：2016

卷号：37

期号：4

起止页码：1198

外文期刊名：POLYMER COMPOSITES

收录：;EI(收录号：20150100398079);WOS:【SCI-EXPANDED(收录号:WOS:000372977000028)】；

基金：Contract grant sponsor: National Nature Science Foundation of China; contract grant number: 50973028; contract grant sponsor: Innovation Program of Shanghai Municipal Education Commission; contract grant number: 12ZZ049; contract grant sponsor: Fundamental Research Funds for the Central Universities.

语种：英文

外文关键词：Coupling agents - Aromatic compounds - Crosslinking - Fibers - Vegetable oils - Adhesion - Epoxy resins

摘要：Poly(p-phenylene benzobisoxazole) (PBO) fiber with a smooth surface exhibits limited interfacial interaction with resin matrix. One of the effective strategies to improve the adhesion between the fiber and resin matrix is through surface modification of the fiber. In this study, we have proposed a novel surface treatment agent based on phosphoester cross-linked castor oil (PCCO) for effective surface treatment of PBO fibers. The surface treatment agent was prepared by a simple cross-linking reaction between hydroxy phosphorylated castor oil (PCO) and epoxy resin, with alcohol as the solvent at 65 degrees C. Once the PBO fiber was treated with this agent, the interfacial adhesion between the PBO fiber and the epoxy resin could then be improved. Systematic analyses suggest that the surface treatment with (PCO 1 epoxy)/alcohol solution improves the interaction of the PBO fiber with the epoxy resin matrix. The PCCO coated onto the surface of PBO fiber acts as a coupling agent, improving the interfacial shear strength (IFSS) of the PBO fiber/epoxy resin composite. Results indicate a 156% increase in IFSS without compromising the mechanical properties of the fiber. (C) 2014 Society of Plastics Engineers