文献类型：期刊文献

英文题名：Masked-Diene Strategy for Constructing Aromatic Ring-Fused Corroles: SOMO(cor)-HOMO(cor) Inversion

作者：Ye, Zhaowen[1];Hu, Mengyi[1];Gong, Danni[1];Li, Qiushuang[1];Luo, Jiesen[1];Liu, Qinlei[1];Liu, Xiujun[1];Li, Qizhao[1];Li, Chengjie[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China

年份：2026

卷号：28

期号：25

起止页码：8240

外文期刊名：ORGANIC LETTERS

收录：;Scopus(收录号：2-s2.0-105043779274);WOS:【SCI-EXPANDED(收录号:WOS:001792664100001)】；

基金：We warmly dedicate this paper to Professor Bernhard Krautler on the occasion of his 80th birthday. This work is financially supported by the Natural Science Foundation of Shanghai (23ZR1415600), the Science and Technology Commission of Shanghai Municipality (24DX1400200), the National Natural Science Foundation of China (22075077, 22571085, and 22131005), the Shanghai Rising-Star Program (23QA1402100), the Shanghai Pujiang Program (24PJD024), and the Fundamental Research Funds for the Central Universities.

语种：英文

摘要：A sulfolenocorrole (i.e., masked corrole-diene)-based "cycloaddition-metalation-oxidation" method has been developed, enabling the synthesis of aromatic ring-fused corroles with yields of up to 86%. Peripheral fusions not only enhance the long wavelength absorption but also modulate the electronic configurations of the ground states. Notably, aromatic ring-fused corroles with open-shell singlet ground states show SOMO(cor)-HOMO(cor) inversion.