文献类型：期刊文献

英文题名：Ligand-controlled copper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes

作者：Li, Jialu[1];Liu, Chuan[1];He, Jingjing[1];Xu, Sixue[1];Zhao, Xianghu[1];Zhu, Yue[1];Cao, Song[1]

机构：[1]East China Univ Sci & Technol ECUST, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China

年份：2020

卷号：7

期号：12

起止页码：1495

外文期刊名：ORGANIC CHEMISTRY FRONTIERS

收录：;EI(收录号：20202708894360);WOS:【SCI-EXPANDED(收录号:WOS:000542743600009)，CCR-EXPANDED(收录号:WOS:000542743600009)】；

基金：We are grateful for financial support from the National Key Research and Development Program of China (No. 2017YFD0200505).

语种：英文

外文关键词：Copper - Regioselectivity - Catalysis - Chelation

摘要：A novel ligand-controlled highly regioselective synthesis of CF3-substituted homopropargylboronates and homoallenylboronatesviacopper-catalyzed 1,2 or 1,4-protoborylation of 2-trifluoromethyl-1,3-conjugated enynes with B(2)pin(2)was developed.