文献类型：期刊文献

英文题名：Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ²N,N′)copper(II)

作者：Yin, Xin

机构：[1]E China Univ Sci & Technol, Dept Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2011

卷号：67

起止页码：M564

外文期刊名：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000291308300041)】；

基金：This work was supported by the College of Chemistry and Molecular Engineering, East China University of Science and Technology.

语种：英文

摘要：In the title compound, [Cu(C7H4FO2)(2)(C12H8N2)(H2O)], the coordination around the Cu-II atom is square-pyramidal. The equatorial positions are occupied by two N atoms from a 1,10-phenanthroline ligand [Cu-N = 2.008 (3) and 2.019 (3) angstrom] and two O atoms from 3-fluorobenzoate ligands and a water molecule [Cu-O = 1.950 (2) and 1.978 (2) angstrom]. One O atom from another 3-fluorobenzoate ligand occupies the apical positon [Cu-O = 2.210 (2) angstrom]. Hydrogen bonds occur between coordinated water molecules and benzoate ligands, while O-H center dot center dot center dot O, C-H center dot center dot center dot O, C-H center dot center dot center dot F and pi-pi stacking [centroid-centroid distance = 3.731 (2) angstrom] interactions consolidate the crystal packing.