详细信息

Lewis Acid Catalyzed Cascade Reactions of Diarylvinylidenecyclopropanes and 1,1,3-Triarylprop-2-yn-1-ols or Their Methyl Ethers  ( SCI-EXPANDED收录 EI收录)  

文献类型:期刊文献

英文题名:Lewis Acid Catalyzed Cascade Reactions of Diarylvinylidenecyclopropanes and 1,1,3-Triarylprop-2-yn-1-ols or Their Methyl Ethers

作者:Shi, Min[1,2];Yao, Liang-Feng[2]

机构:[1]Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China;[2]E China Univ Sci & Technol, Shanghai 200237, Peoples R China

年份:2008

卷号:14

期号:28

起止页码:8725

外文期刊名:CHEMISTRY-A EUROPEAN JOURNAL

收录:;EI(收录号:20084311651732);WOS:【SCI-EXPANDED(收录号:WOS:000260035900035)】;

基金:We thank the Shanghai Municipal Committee of Science and Technology (04JC14083. 06XD14005). Chinese Academy of Sciences (KGCX2-210-01). and the National Natural Science Foundation of China for financial support (20472096, 203900502. 20672127. and 20732008).

语种:英文

外文关键词:alkynes; domino reactions; Friedel-Crafts reaction; indenes; Meyer-Schuster rearrangement; naphthalenes

摘要:The reactions of vinylidene-cyclopropanes 1 with 1,1,3-triarylprop-2-yn-1-ols or their methyl ethers 2 in the presence of a Lewis acid selectively produce 4-dihydro-1H-cyclopenta[b]-naphthalene derivatives 3 or 1,2,3,8-tetrahydrocyclopenta[a]indene derivatives 4 depending on the substituents on the cyclopropane. Good to high yields are

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