文献类型：期刊文献

英文题名：Synthesis and CO2 adsorption characteristics of lithium zirconates with high lithia content

作者：Yin, Xian-Sheng[1]; Li, Shao-Peng[1]; Zhang, Qin-Hui[1]; Yu, Jian-Guo[1]

机构：[1] State Key Lab of Chemical Engineering, College of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China

年份：2010

卷号：93

期号：9

起止页码：2837

外文期刊名：Journal of the American Ceramic Society

收录：EI(收录号：20103713225329)

语种：英文

外文关键词：Carbon dioxide - Thermogravimetric analysis - Lithium compounds - Lithium - Scanning electron microscopy - Temperature - X ray diffraction

摘要：Pure monoclinic phase Li6Zr2O7 and rhombohedral phase Li8ZrO6 that coexisted with a fraction of Li6Zr2O7, are synthesized by a liquid phase coprecipitation method and characterized by X-ray diffraction, scanning electron microscopy, and thermo-gravimetric analysis. The high-temperature CO 2 uptake properties of both samples are systematically investigated. The temperature effect tests indicate that, in the case of low temperature (2 uptake rates because of the inhibited diffusion of CO2 in the solid carbonate shell; while at the temperature above the melting point of Li2CO 3 (about 983 K), the CO2 uptake rates are enhanced dramatically for both Li6Zr2O7 and Li 8ZrO6, and achieved about 12.3% weight gain and 35.0% weight gain within 15 min at 1073 K, respectively. The thermal stability tests indicate that both samples exhibit gradually reduced capacities during the multicycle processes. The analysis of the crystalline structure reveals that the reduced capacities are resulted from the loss of lithia under high temperatures. Finally, the possible adsorption pathways for both monoclinic phase Li6Zr2O7 and rhombohedral phase Li 8ZrO6 are suggested as well. ? 2010 The American Ceramic Society.