文献类型：期刊文献

英文题名：Long-range coordination engineering in nickel single-atom catalysts to boost the electroreduction of CO2

作者：Peng, Mingxia[1];Li, Jing[1];Zhu, Sili[1];Li, Fengrui[1];Kang, Mengde[1];Liu, Honglai[1,2];Lian, Cheng[1,2];Li, Jingkun[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2025

卷号：61

期号：95

起止页码：18854

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;EI(收录号：20254819593303);WOS:【SCI-EXPANDED(收录号:WOS:001606670400001)】；

基金：This work was financially supported by the National Natural Science Foundation of China (22102114).

语种：英文

外文关键词：Carbon dioxide - Catalyst activity - Cobalt compounds - Nickel compounds

摘要：The practical application of Ni-single atom catalysts (Ni-SACs) is hindered by their insufficient intrinsic activity. Long-range coordination engineering via Cl/S doping in the higher-order coordination shells (>= 2) effectively modulates the electronic structure of Ni-SACs to strengthen the *COOH binding, thereby enhancing eCO2RR activity toward CO.