文献类型：期刊文献

英文题名：Monocarboxylation and Intramolecular Coupling of Butenylated Arenes via Palladium-Catalyzed C-H Activation Process

作者：Liu, Rui[1,2];Lu, Ze-Hai[1,2];Hu, Xiao-Hui[1,2];Li, Jun-Li[1,2];Yang, Xian-Jin[1,2,3]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

年份：2015

卷号：17

期号：6

起止页码：1489

外文期刊名：ORGANIC LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000351558100036)，CCR-EXPANDED(收录号:WOS:000351558100036)】；

基金：We are grateful to the National Natural Science Foundation of China (NSFC) (Grant Number 21372077) for financial support.

语种：英文

摘要：A novel and practical reaction for the direct intramolecular oxidative coupling of butenylated arenes is reported. With the catalysis of Pd(OAc)(2), reactions of various butenylated arenes and carboxylic acids with Selectfluor reagent in CH3CN solution afforded the corresponding monocarboxylation/cyclization products in good yields under mild conditions. This research demonstrated an economic method with the synthesis of 2-tetralyl carboxylic esters, a valuable class of bioactive compounds.