文献类型：期刊文献

中文题名：金属卤化物配合物催化芳胺烷硫化反应的研究

英文题名：Alkylthiolation of Aromatic Amine with Metal-halogen Complexes

作者：王延飞[1];凌昊[1];沈本贤[1]

机构：[1]华东理工大学化工学院

年份：2004

卷号：30

期号：3

起止页码：241

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;EI(收录号：2004358330447);Scopus;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：二胺基甲苯;二甲基二硫;配位催化剂;选择性

外文关键词：toluenediamine; dimethyl disulfide; coordination catalyst; selectivity

摘要：以2,4-二胺基甲苯(TDA)和二甲基二硫为原料,以卤化亚铜配合物为催化剂,制备二甲硫基2,4-二胺基甲苯(DMTDA)。考察了工艺参数对制备DMTDA的收率和选择性的影响,适宜的工艺条件是:在常压下反应温度为150°C,反应时间为6h,催化剂与TDA的摩尔比为0.05。由实验还可知配位催化剂失活是由于二甲基二硫与催化剂中的部分配体发生了反应,催化剂配体的流失是催化剂活性降低的主要原因。
Activity of a copper-halogen coordination catalyst used to prepare dimethyl-(thioltoluenediamine)(DMTDA) is estimated. This paper describes the inactivity reasons of complex catalyst and factors affecting the alkylthiolation of toluenediamine. When the agitator speeds is higher and catalyst grains are finer, catalysis powder particles are suspended in the mixture with a state of pseudo-homogenous suspension, the mass-transfer resistances at the outer surface of the catalyst and inside the catalyst are considered to be negligible, on the condition of which the alkylthiolation of toluenediamine is considered to be carried out in pseudo-homogenous system. Higher yield and selectivity of DMTDA are reached when the reaction temperature is 150 (°C), the mole ratio of catalyst to TDA is 0.05 and reaction time is about 6 h under the atmosphere. The experiment results show that loss of coordination from coordination catalyst results from the inactivity of catalysts.