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Effect of interfacial properties on the stability of ultra-dry CO2-in-water (C/W) foams stabilized with zwitterionic surfactants and nonionic/anionic polymers: Experimental and DPD simulation  ( EI收录)  

文献类型:期刊文献

英文题名:Effect of interfacial properties on the stability of ultra-dry CO2-in-water (C/W) foams stabilized with zwitterionic surfactants and nonionic/anionic polymers: Experimental and DPD simulation

作者:Ma, Liru[1]; Bao, Lei[1]; Hu, Dongdong[1]; Zhao, Ling[1]; Liu, Tao[1]

机构:[1] Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China

年份:2020

卷号:158

外文期刊名:Journal of Supercritical Fluids

收录:EI(收录号:20195207904639)

语种:英文

外文关键词:Amides - Nonionic surfactants - Carbon dioxide

摘要:Cocamidopropyl betaine (CAPB) and poly(acrylamide) (PAM) were used for the formation of an ultra-dry CO2-in-water (C/W) foam in which the water volume fraction could be as low as 5 %. At water contents between 10 % and 5 % v/v, the C/W foam formed with CAPB and nonionic PAM (NPAM) showed four times longer stabilization times than that formed with only CAPB. The synergistic effect of surfactants and polymers on the viscosity, interfacial density and thickness was also analysed using dissipative particle dynamics (DPD) simulations. NPAM could assemble at the C/W interface, act as a surfactant and stretch between surfactants, which enhanced the density of the surfactant at the interface, prevented the aggregation between the surfactants and improved the foam stability. For the CO2/water/CAPB system, the addition of NPAM with a shorter chain length was more conducive to improve the stability of the C/W foam. ? 2019 Elsevier B.V.

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