文献类型：期刊文献

英文题名：Efficient CO2 capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups

作者：Zhu, Xiang[1,2,3];Mahurin, Shannon M.[3];An, Shu-Hao[1,2];Chi-Linh Do-Thanh[4];Tian, Chengcheng[1,2,3];Li, Yankai[1,2];Gill, Lance W.[3];Hagaman, Edward W.[3];Bian, Zijun[1,2];Zhou, Jian-Hai[1,2];Hu, Jun[1,2];Liu, Honglai[1,2];Dai, Sheng[3,4]

机构：[1]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China;[3]Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA;[4]Univ Tennessee, Dept Chem, Knoxville, TN 37916 USA

年份：2014

卷号：50

期号：59

起止页码：7933

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000338439700003)】；

基金：XZ, JH and HLL thank the National Basic Research Program of China (2013CB733501), the National Natural Science Foundation of China (No. 91334203, 21176066), the 111 Project of China (No. B08021) and the Fundamental Research Funds for the Central Universities of China. This work was also supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division.

语种：英文

摘要：A porous triazine and carbazole bifunctionalized task-specific polymer has been synthesized via a facile Friedel-Crafts reaction. The resultant porous framework exhibits excellent CO2 uptake (18.0 wt%, 273 K and 1 bar) and good adsorption selectivity for CO2 over N-2.