文献类型：期刊文献

英文题名：Pyrite-Assisted Degradation of Methoxychlor by Laccase Immobilized on Fe3s4/Ew-Msio2

作者：Yang, Yuxiang[1]; Yang, Jiaqi[1]; Huang, Yan[1]; Yuan, Hongming[3]; Zhao, Yi[1]; Liu, Xiangnong[4]; Ni, Chaoying[2]

机构：[1] School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China; [2] Jilin University, China; [3] State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, China; [4] Analysis Test Center, Yangzhou University, Yangzhou, 225009, China

年份：2023

外文期刊名：SSRN

收录：EI(收录号：20230084285)

语种：英文

外文关键词：Activation energy - Degradation - Enzymes - Mass spectrometry - Pyrites - Silica - Silicon

摘要：Laccase immobilized and cross-linked on Fe3S4/earthworm-like mesoporous SiO2 (Fe3S4/EW-mSiO2), was used to degrade methoxychlor (MXC) in aqueous environments. The effects of various parameters on the degradation of MXC were determined using free and immobilized laccase. Immobilization improved the thermal stability and reuse of laccase significantly. Under the optimum conditions, the degradation rate of MXC by immobilized laccase reached a maximum value of 40.99% and remained at 1/3 of the original after six cycles. The excellent degradation performance of Fe3S4/EW-mSiO2 was attributable to the pyrite (FeS2) impurity in Fe3S4 acting as an electron donor in reductive dehalogenation. Sulfide groups and Fe2+ reduced the activation energy of the system resulting in pyrite-assisted degradation of MXC. The degradation mechanism of MXC in aqueous environments by laccase immobilized on Fe3S4/EW-mSiO2 was determined via mass spectroscopy of the degradation products. ? 2023, The Authors. All rights reserved.