文献类型：期刊文献

英文题名：Enantioselective intramolecular Rauhut-Currier reaction catalyzed by chiral phosphinothiourea

作者：Gong, Jing-Jing[1,2];Li, Tian-Ze[1,2];Pan, Kun[1,2];Wu, Xin-Yan[1,2,3]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

年份：2011

卷号：47

期号：5

起止页码：1491

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000286389500027)，CCR-EXPANDED(收录号:WOS:000286389500027)】；

基金：We are grateful for the financial support from National Natural Science Foundation of China (20772029), the Program for New Century Excellent Talents in University (NCET-07-0286), and the Fundamental Research Funds for the Central Universities.

语种：英文

摘要：Chiral organophosphine-catalyzed enantioselective Rauhut-Currier reaction has been disclosed for the first time. With L-valine-derived phosphinothiourea, the intramolecular Rauhut-Currier reaction of bis(enones) was achieved in good yields (up to 99%) with excellent enantioselectivities (up to 99.4% ee).