文献类型：期刊文献

英文题名：Pd(OAc)2/PPh3-Catalyzed Desulfonylative Homocoupling of Arylsulfonyl Chlorides

作者：Zhao, Qiao[1];Chen, Liangshun[1];Lang, Hongyue[1];Wu, Shengying[1];Wang, Limin[1,2]

机构：[1]E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

年份：2015

卷号：33

期号：5

起止页码：535

外文期刊名：CHINESE JOURNAL OF CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000354572800006)，CCR-EXPANDED(收录号:WOS:000354572800006)】；

基金：The work was supported by the National Natural Science Foundation of China (Nos. 21272069, 20672035), the Fundamental Research Funds for the Central Universities, and the Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

语种：英文

外文关键词：biaryls; arylsulfonyl chlorides; desulfonylative; palladium-catalyzed

摘要：The Pd-catalyzed homodimerization with respect to arylsulfonyl chlorides as an efficient method for the synthesis of biaryls has been developed. This desulfonylative reaction which was performed at reflux in 1,4-dioxane for 4 h under air afforded the desired products in good to excellent yields.