文献类型：期刊文献

英文题名：Synthesis and crystal structure of the complex of antimony trichloride and dioxane

作者：Zang, XS; Chen, YR; Luan, SR; Zhong, GQ; Guo, YC

机构：[1]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China;[2]Sichuan Inst Anim Husb & Vet Med, Chongqing 402460, Peoples R China;[3]Nanyang Teachers Coll, Dept Chem, Nanyang 473061, Peoples R China

年份：2001

卷号：17

期号：6

起止页码：901

外文期刊名：CHINESE JOURNAL OF INORGANIC CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000172081500024)】；

语种：英文

外文关键词：dioxane complex of antimony trichloride synthesis; crystal structure

摘要：New solid complex of the antimony trichloride and dioxane was obtained through a reaction of the dioxane and the absolute methanol solution of the antimony trichloride. The formula of the complex is [SbCl3 . {(CH2)(4)O-2}(1.5)]. The crystal structure of the complex belongs to cubic system, space group I-43d, a = 17.1417 (5) Angstrom, Z = 16. The trivalent antimony ion not only bonds directly to three chlorine anions, but also is coordinated by three oxygen atoms of the dioxane molecules. Two oxygen atoms in a dioxane molecule will coordinate to different antimony ions, respectively.