文献类型：期刊文献

英文题名：Selective S-arylation of thiols with o-OTf-substituted diaryliodonium salts toward diarylsulfides

作者：Zhang, Yuxuan[1]; Wang, Yu[1]; Wang, Limin[1]; Han, Jianwei[1]

机构：[1] Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

年份：2023

卷号：22

期号：3

起止页码：486

外文期刊名：Organic and Biomolecular Chemistry

收录：EI(收录号：20235215290776)

语种：英文

外文关键词：Salts

摘要：In contrast to the previously reported intramolecular aryl migration, we present the selective sulfenylation of ortho-trifluoromethanesulfonate (OTf) substituted diaryliodonium salts with thiols. As such, diarylsulfides bearing vicinal OTf groups were synthesized in good yields. The unique reactivity of the vicinal OTf group and the sulfur atom in arylsulfides offers further transformations. ? 2024 The Royal Society of Chemistry.