文献类型：期刊文献

英文题名：Ortho-Hydroxy-Substituted Diaryliodonium Salts Enabled Intramolecular Aryliodonium Rearrangement in Synthesis of Ortho-Iodo Diaryl Ethers

作者：Liu, Taiyou[1,2];Pan, Cheng[1,2];Wang, Limin[1,2];Xu, Zhen-Jiang[3];Han, Jianwei[1,2]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat, Feringa Nobel Prize Scientist Joint Res Ctr, Sch Chem & Mol Engn,Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China

年份：2025

卷号：90

期号：16

起止页码：5435

外文期刊名：JOURNAL OF ORGANIC CHEMISTRY

收录：;EI(收录号：20251618257155);WOS:【SCI-EXPANDED(收录号:WOS:001467403500001)，CCR-EXPANDED(收录号:WOS:001467403500001)】；

基金：The work was supported by the National Nature Science Foundation of China (NSFC 22478117). The authors thank the Research Center of Analysis and Test of East China University of Science and Technology for the help with the characterization.

语种：英文

摘要：A new family of ortho-hydroxy-substituted diaryliodonium salts was synthesized with 1-acetoxy-2-iodobenzenes, in which the acetyl group was cleaved in a one-pot synthesis. The ortho-hydroxyl-substituted diaryliodonium salts underwent further intramolecular aryl migration reaction, giving ortho-iodo diaryl ethers either with or without the presence of bases.