文献类型：期刊文献

中文题名：新型有机膦均聚物的合成及缓蚀性能的研究

英文题名：Study on the Synthesis of Organophosphonic Homopolymer and Research of Its Ability to Control Corrosion

作者：陈康[1];汪祖模[1];陆仁杰[1];蔡兰坤[1]

机构：[1]华东理工大学环境工程系

年份：1998

卷号：24

期号：1

起止页码：107

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;国家哲学社会科学学术期刊数据库;EI(收录号：1998054218603);Scopus;北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：异丙烯膦酸;有机膦均聚物;缓蚀性能;缓蚀剂

外文关键词：synthesis; isopropenyl phosphonic acid; phosphonic homopolymer; corrosion inhibiting; spinner test

摘要：利用三氯化磷、丙酮、冰乙酸合成了异丙烯膦酸（ＩＰＰＡ）单体，进一步制取了聚异丙烯膦酸，并对其缓蚀性能进行了评定。采用表面分析技术ＸＰＳ，ＡＥＳ，对聚异丙烯膦酸缓蚀机理进行了探讨。
Isopropenyl phosphonic acid (IPPA) has been obtained by the reaction of phosphorus trichloride with aceton in the medium of acetic acid. And polyisopropenyl phosphonic acid (PIPPA) was obtained by the polymerization of IPPA initiated with suitable initiator. The results from spinner test, electrochemical corrosion procedure show that homopolymer PIPPA has an excellect property to inhibit the corrosion of mild steel in tap water. And the surface techniques [Auger electron spectroscopy(AES), X ray photoelectron spectrocopy (XPS)] has been used to research the composition structure and forming mechanism of the protective film on the surface of mild steel coupon. The results show that PIPPA is an excellent agent as corrosion inhibitor in water treatment.