文献类型：期刊文献

英文题名：Synthesis of monofluoroalkenes through selective hydrodefluorination of gem-difluoroalkenes with Red-Al?

作者：Wu, Jingjing[1,3];Xiao, Juan[2];Dai, Wenpeng[2];Cao, Song[2,3]

机构：[1]Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China;[2]E China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

年份：2015

卷号：5

期号：43

起止页码：34498

外文期刊名：RSC ADVANCES

收录：;EI(收录号：20151700774251);WOS:【SCI-EXPANDED(收录号:WOS:000353167500099)】；

基金：We are grateful for financial supports from the National Natural Science Foundation of China (Grant no. 21302128, 21272070).

语种：英文

外文关键词：Catalysts - Aluminum compounds

摘要：A novel and practical approach for the selective hydrodefluorination of gem-difluoroalkenes using Red-Al (R) as a reductant at room temperature in CH2Cl2 without any additional base and metal catalyst was reported. Various monofluoroalkenes were obtained in moderate to high yields with good E-selectivity.