文献类型：期刊文献

英文题名：Recent advances in heterogeneous catalytic conversion of glucose to 5-hydroxymethylfurfural via green routes

作者：Wang, Jianjian[1,2];Xi, Jinxu[1];Xia, Qineng[1];Liu, Xiaohui[1];Wang, Yanqin[1]

机构：[1]East China Univ Sci & Technol, Res Inst Ind Catalysis, Key Lab Adv Mat, Shanghai 2002037, Peoples R China;[2]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia

年份：2017

卷号：60

期号：7

起止页码：870

外文期刊名：SCIENCE CHINA-CHEMISTRY

收录：;EI(收录号：20172003671329);WOS:【SCI-EXPANDED(收录号:WOS:000404713100005)】；

基金：This work was supported by the National Natural Science Foundation of China (91545103, 21273071, 21403065), and the Commission of Science and Technology of Shanghai Municipality (10dz2220500).

语种：英文

外文关键词：5-hydroxymethylfurfural; glucose; heterogeneous catalysis; green route

摘要：With concerns of diminishing fossil fuel reserves and environmental deterioration, great efforts have been made to explore novel approaches of efficiently utilizing bio-renewable feedstocks to produce chemicals and fuels. 5-Hydroxymethylfurfural (HMF), generated from dehydration of six-carbon ketose, is regarded as a primary and versatile renewable building block to realize the goal of production of these high valued products from renewable biomass resources transformation. In this review, we summarize the recent advances via green routes in the heterogeneous reaction system for the catalytic production of HMF from glucose conversion, and emphasize reaction pathways of these reaction approaches based on the fundamental mechanistic chemistry as well as highlight the challenges (such as separation and purification of products, reusing and regeneration of catalyst, recycling solvent) in this field.