文献类型：期刊文献

中文题名：煤与生物质共液化的催化反应

英文题名：Catalysis Coliquefaction of Coal and Biomass

作者：白鲁刚[1];颜涌捷[1];李庭琛[1];任铮伟[1]

机构：[1]华东理工大学能源化工系,上海200237

年份：2000

卷号：21

期号：2

起止页码：198

中文期刊名：化工冶金

外文期刊名：Huagong Yejin/Engineering Chemistry & Metallurgy

收录：EI(收录号：2000075252818);北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金!(编号:29776015)

语种：中文

中文关键词：煤;生物质;催化剂;硫铁化物;共液化;油产率

外文关键词：coal, biomass, catalyst; ferric sulfide; coliquefaction, oil yield; conversion

摘要：从有效性和经济角度考虑，选定硫铁化物为煤与生物质加氢共液化的催化剂．在不同条件下制备的催化剂对反应有不同的催化效果．硫铁催化剂可降低反应苛刻度，在３００～４００℃范围内可明显提高反应转化率和油产率．建议合适的反应条件为：温度３５０℃；反应时间 ２０ ｍｉｎ，初始冷氢压 ３．４０ ＭＰａ．
After selection of suitable catalyst for coliquefaction of coal and biomass, ferric sulfide (FeSx) has been determined as an applicable catalyst from the aspects of effectiveness and economy. The catalysts prepared under different conditions have different effects on the reaction. The ferric sulfide catalyst cannot only reduce the seventy of reaction condition, but also significantly improve the conversion and oil yield in the temperature range of 300-400℃. The completeness time of coliquefaction can be shortened with the presence of this catalyst. Reaction temperature has a notable effect on catalytic coliquefaction. And cool hydrogen pressure plays a more tangible role during catalystic coliquefaction than non-catalytic reaction. The preferable reaction conditions are: temperature 350℃, reaction time 20 min, cool H2 pressure 3.40 MPa.