文献类型：期刊文献

中文题名：Co-Fe普鲁士蓝类配合物纳米颗粒的微乳液法制备与表征(英文)

英文题名：Synthesis and Characterization of Cobalt-iron Prussian Blue Analogue Nanoparticles by Microemulsion

作者：方建[1];杜贤龙[1];吕辉鸿[1];郭丹[1];赵继华[1];沈伟国[2]

机构：[1]兰州大学化学化工学院,兰州730000;[2]华东理工大学化学学院,上海200237

年份：2007

卷号：23

期号：5

起止页码：923

中文期刊名：无机化学学报

外文期刊名：Chinese Journal of Inorganic Chemistry

收录：CSTPCD;;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000246718900035)】；北大核心:【北大核心2004】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金资助项目(No.20603014,20473035)。

语种：中文

中文关键词：微乳液;Triton;X-100;普鲁士蓝类配合物;纳米颗粒

外文关键词：microemulsion; Triton X-100; Prussian blue analogues; nanoparticle

摘要：Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether (TritonX-100)/n-hexanol/cyclohexane microemulsion. The effects of the water-to-surfactant molar ratio (w), the reactant concentration and the reaction temperature on the morphology of cobalt-iron Prussian blue analogues were studied. The samples were characterized by transmission electron microscopy (TEM), field emission scan electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and infrared spectroscopy (IR).
Highly oriented cubic, hollow cubic and spherical nanoparticles of cobalt-iron Prussian blue analogues were synthesized in poly oxyethylene tertoctylphenyl ether （TritonX-100）/n-hexanol/cyclohexane microemulsion. The effects of the water-to-surfactant molar ratio （w）, the reactant concentration and the reaction temperature on the morphology of cobalt-iron Prussian blue analogues were studied. The samples were characterized by transmission electron microscopy （TEM）, field emission scan electron microscopy （FE-SEM）, energy-dispersive Xray spectroscopy （EDS）, X-ray diffraction （XRD） and infrared spectroscopy （IR）.