文献类型：期刊文献

中文题名：New insights into the pre-lithiation kinetics of single-crystalline Ni-rich cathodes for long-life Li-ion batteries

作者：Qiang Han[1];Lele Cai[2];Zhaofeng Yang[2];Yanjie Hu[1];Hao Jiang[1,2];Chunzhong Li[1,2]

机构：[1]Shanghai Engineering Research Center of Hierarchical Nanomaterials,School of Chemical Engineering,East China University of Science and Technology,Shanghai,200237,China;[2]Key Laboratory for Ultrafine Materials of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai,200237,China

年份：2024

卷号：9

期号：3

起止页码：556

中文期刊名：Green Energy & Environment

外文期刊名：绿色能源与环境（英文版）

收录：CSTPCD;;Scopus;CSCD:【CSCD2023_2024】；

基金：supported by the National Natural Science Foundation of China(21975074,91834301);the Innovation Program of Shanghai Municipal Education Commission;the Fundamental Research Funds for the Central Universities.

语种：英文

中文关键词：Single-crystalline cathode;Ni-rich oxides;Pre-lithiation;Li-ion batteries;Surface modification

摘要：Developing single-crystalline Ni-rich cathodes is an effective strategy to improve the safety and cycle life of Li-ion batteries(LIBs).However,the easy-to-loss of Li and O in high-temperature lithiation results in unsatisfactory ordered layered structure and stoichiometry.Herein,we demonstrate the synthesis of highly-ordered and fully-stoichiometric single-crystalline LiNi_(0.83)Co_(0.12)Mn_(0.05)O_(2)(SC-NCM83)cathodes by the regulation of pre-lithiation kinetics.The well-balanced pre-lithiation kinetics have been proved to greatly improve the proportion of layered phase in the intermediate by inhibiting the formation of metastable spinel phase,which promoted the rapid transformation of the intermediate into highly-ordered layered SC-NCM83 in the subsequent lithiation process.After coating a layer of Li_(2)O–B_(2)O_(3),the resultant cathodes deliver superior cycling stability with 90.9%capacity retention at 1C after 300 cycles in pouch-type full batteries.The enhancement mechanism has also been clarified.These findings exhibit fundamental insights into the pre-lithiation kinetics process for guiding the synthesis of high-quality singlecrystalline Ni-rich cathodes.