文献类型：期刊文献

英文题名：In situ formation of zinc phthalate as a highly dispersed β-nucleating agent for mechanically strengthened isotactic polypropylene

作者：Qin, Wei[1];Xin, Zhong[1];Pan, Chunmeng[1];Sun, Shibao[1];Jiang, Xiaofeng[1];Zhao, Shicheng[1]

机构：[1]East China Univ Sci & Technol, Sch Chem Engn, Shanghai Key Lab Multiphase Mat Chem Engn, State Key Lab Chem Engn,Dept Prod Engn, 130 Mei Long Rd, Shanghai 200237, Peoples R China

年份：2019

卷号：358

起止页码：1243

外文期刊名：CHEMICAL ENGINEERING JOURNAL

收录：;EI(收录号：20184305973881);WOS:【SCI-EXPANDED(收录号:WOS:000450105700117)】；

基金：This work was financially supported by the National Natural Science Foundation of China (Grants 21476085 and 21878089), National Key R&D Program of China (2016YFB0302201) and the Fundamental Research Funds for the Central Universities (22221818014). The authors greatly appreciate Professor Shiao-Wei Kuo of National Sun Yat-Sen University for his fruitful discussions on the experiments and his guidance on the writing of the paper.

语种：英文

外文关键词：Polypropylene; beta-Nucleating agent; Zinc phthalate; Crystallization; Dispersion

摘要：Introducing beta-nucleating agents (beta-NAs) is a convenient and reliable method for obtaining isotactic polypropylene (iPP) having a high beta-crystal content. Nevertheless, the poor dispersion and agglomeration of beta-NAs limit their nucleation efficiency. In this paper, a new strategy-involving in situ generation of beta-NAs-is described to improve the dispersion of NAs in the polymer matrix. Here, zinc phthalate (ZnPht) is reported as a new beta-NA for iPP; the self-dispersed ZnPht(IS) was generated in situ by adding its reaction precursors-phthalic anhydride (Pht) and zinc oxide (ZnO)-during the extrusion of iPP. Compared with the situation involving the pre-addition of ZnPht, the use of ZnPht(IS) resulted in a higher nucleation efficiency and greater selectivity toward the beta-crystal form; indeed, the content of beta-crystal forms (k beta) improved from 0.74 for ZnPht/iPP to 0.97 for ZnPht(IS)/iPP. Moreover, the impact strength of the iPP prepared using 0.2 wt% ZnPht(IS) was nearly 2.9 times greater than that of neat iPP; for the iPP nucleated with ZnPht, it was approximately 2.0 times greater at the same loading content. To explain these phenomena, we propose a new mechanism for the self-dispersion of beta-NA during its in situ generation; evidence from Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy was consistent with our proposed mechanism. This strategy and method of preparing beta-NA in situ has several attractive features that should encourage the production and application of beta-iPP. Furthermore, this strategy might potentially be extended to solve the issues of poor dispersion and serious agglomeration for other additives in other polymers.