文献类型：期刊文献

英文题名：Copper(I) Iodide Catalyzed Cyanation of N-Heteroaryl Bromides Using Potassium Hexacyanoferrate(II)

作者：Cai Liangzhen[1];Liu Bin[1];Dong Yuhu[1];Du Guangyan[1];Tao Xiaochun[1]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2009

卷号：67

期号：21

起止页码：2523

外文期刊名：ACTA CHIMICA SINICA

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000272761100021)】；

语种：英文

外文关键词：potassium hexacyanoferrate(II); cyanation; N-isopropylimidazole; N,N '-dimethylethylenediamine; N-heteroaryl nitrite

摘要：An efficient and user-friendly synthesis for a series of N-heteroaryl nitrites is described. This process is based on the Cut catalyzed cyanation of N-heteroaryl bromides with K-4[Fe(CN)(6)] in the presence of N-isopropylimidazole and N,N'-dimethylethylenediamine. The results show that the reaction has good to high yields.