文献类型：期刊文献

英文题名：Confusion Approach Modulated Syntheses of Corrorin Parasitized Hexaphyrins(1.1.1.1.1.0) and the Oxidative Ring Cleavage Behavior

作者：Xu, Yue[1];Zhu, Bin[1];Li, Qizhao[1,3];Baryshnikov, Glib[2];Zhou, Mingbo[3];Li, Chengjie[1];Sha, Feng[1];Wu, Xinyan[1];Agren, Hans[4];Song, Jianxin[3];Xie, Yongshu[1]

机构：[1]East China Univ Sci & Technol, Sch Pharm,Shanghai Key Lab Funct Mat Chem,Lab Pha, Sch Chem & Mol Engn,State Key Lab Bioreactor Engn, Key Lab Adv Mat & Inst Fine Chem,Inst Fine Chem, Shanghai 200237, Peoples R China;[2]Linkoping Univ, Lab Organ Elect, Dept Sci & Technol, SE-60174 Norrkoping, Sweden;[3]Hunan Normal Univ, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Changsha 410081, Peoples R China;[4]Uppsala Univ, Dept Phys & Astron, SE-75120 Uppsala, Sweden

年份：2021

卷号：23

期号：21

起止页码：8307

外文期刊名：ORGANIC LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000716793100038)】；

基金：This work was financially supported by the NSFC (Grants 21772041, 21971063, and 22075077), the Program of Shanghai Academic Research Leader (Grant 20XD1401400), the Natural Science Foundation of Shanghai (Grant 20ZR1414100), the Science and Technology Planning Project of Hunan Province (Grant 2018TP1017), and the Fundamental Research Funds for the Central Universities (Grant 222201717003). G.B. is thankful for the Swedish National Infrastructure for Computing (SNIC) resources at the HighPerformance Computing Center North (HPC2N) and financial support of the Swedish Research Council (Grants 2018-05973 and 2020-04600). The authors thank the Research Center of Analysis and Test of East China University of Science and Technology for the help on the characterization.

语种：英文

摘要：A corrorin parasitized hexaphyrin(1.1.1.1.1.0) 1 was synthesized by [4 + 4] condensation, and subsequent treatment with PbO2 afforded hexaphyrin 2 appended with a dipyrrinone moiety via regioselective opening of the corrorin ring. In contrast, oxidation of the corresponding corrorin-N-confused hexaphyrin(1.1.1.1.1.0) hybrid 3 afforded only a keto adduct 4. As a result, the planarity and aromaticity of the hexaphyrin moiety can be modulated.